引言:奇特的“不粘”粘合剂
这是一种我见过的最奇特的材料之一。
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This is one of the strangest materials I have ever seen.
它完全不粘。
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It is not sticky at all.
你甚至无法将普通胶带粘在上面。
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You can't even stick regular tape to it.
但如果我把它铺在这颗番茄上,它就能把它托起来,除非你把它倒过来,那样它就会掉下来。
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But if I drape it over this tomato, it holds it up, unless you turn it upside-down, in which case it just falls off.
那么它只粘水果吗?
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Now does it only stick to fruit?
不,它能粘住水瓶或一袋薯片,基本上任何近似光滑的表面。
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No, it'll stick to a water bottle or a bag of chips, basically any approximately smooth surface.
这是因为这种材料是模仿壁虎皮肤制造的。
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And that's because this material is made to mimic gecko skin.
人工壁虎皮肤来自斯坦福大学(Stanford University: 位于美国加州的私立研究型大学)马克·卡特科斯基(Mark Cutkosky)教授的实验室,现在已被用于机器人抓手、能拉动远超自身重量的微型机器人、在国际空间站(International Space Station: 围绕地球运行的载人空间站)漂浮的机器人,甚至能让一个人像蜘蛛侠一样攀爬玻璃墙。
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Artificial gecko skin comes out of Professor Mark Cutkosky's Stanford lab and it has now been used on robotic grippers, on tiny robots that can pull way more than their weight, on a robot that floats around the International Space Station and even enabling a person to scale a glass wall, Spider-man style.
这一切都始于一场制造一个无需吸力即可攀爬垂直墙壁的机器人的竞赛。
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It all started with a competition to make a robot that climbs a vertical wall without suction.
壁虎粘合的奥秘:范德华力
Mark: 这是普通胶带。
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Here's sticky type.
每个人都熟悉它。
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Everybody's familiar with it.
你按上去,它就粘住了。
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You press it on and it sticks.
实际上粘得很牢。
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Sticks pretty hard actually.
然后你把它撕下来。
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And then you peel it off.
这是壁虎材料。
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Here's gecko material.
你首先注意到的是它实际上……它一点也不粘,但如果我从中间提起它,我能举起一个足球。
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And the first thing you notice is that it's actually... It's not sticky at all, but if I lift it from the middle I can lift a football.
你可能会说:“嗯,如果你有那种粘性胶带也能做到”,对吧?
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You might say, "Well you could do that if you had this other sticky tape", right?
嗯,是的,但如果我有那种粘性胶带,它就不会这样做。
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Well, yes, but if I had the other sticky tape it wouldn't do that.
这很重要,因为如果你是一个试图爬墙的小型机器人,你不能让脚上粘着像口香糖一样的东西,因为那样你每走一步都需要付出努力。
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And that's important because if you're a small robot trying to climb a wall, you can't afford to have something like chewing gum on your feet, 'cause then every step you take is effort.
你想要的是一种只在你需要时才抓取的东西,这正是我们受壁虎启发的粘合剂的主要原理。
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What you want is something that only grabs when you need it to, and that's kind of the main principle of our gecko-inspired adhesive.
这是一个早期原型,是受壁虎启发的“粘性机器人”。
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Here this is an early prototype of the sticky bot gecko-inspired robot.
这让我们长期致力于理解是什么让壁虎的附着力发挥作用,即拥有抓力但又不粘的东西。
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This got us into a a long effort to understand what is it that makes gecko adhesion work, having something which grips but is not sticky.
Derek: 壁虎是令人难以置信的攀爬者。
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Geckos are incredible climbers.
它们能爬墙甚至在天花板上行走,但很长一段时间我们都不知道它们是如何做到的。
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They scale walls and even walk on ceilings, but for a long time we didn't know how they did it.
它们不像蜘蛛或其他昆虫那样使用毛发或尖刺。
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They don't use hairs or spikes like spiders or other insects.
你可能会认为它们的脚尖有微小的吸盘,但它们的附着力实际上比吸盘强得多。
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You might think they'd have tiny little suction cups at the end of their feet, but their adhesion is actually way stronger than suction cups.
Mark: 一只壁虎可以轻易地只用一个脚趾的一部分挂住它整个身体的重量。
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A gecko can easily hang its entire weight from just part of one toe.
Derek: 如果你放大壁虎的脚趾,就能看到其工作原理的线索。
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The clue to how this works can be seen if you zoom in on a gecko's toe
Mark: 这些被称为层状结构(lamella: 壁虎脚趾下方的褶皱状结构)。
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These are called lamella.
它们是刚毛(seta: 从层状结构中伸出的微小毛发状突起)的区域。
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They're regions of stalks, which are called seta.
而刚毛又分叉成这些极其精细的铲状结构(spatula: 刚毛末端更小的扁平结构),其宽度不到一微米。
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And the seta branch into these incredibly fine structures called spatula, which are less than one micrometer across.
Derek: 这很重要,因为它们用来粘附的物理原理实际上非常微弱。
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And that's important because the physical principle they use to stick is actually incredibly weak.
它不像离子键那样,原子因一个带正电而另一个带负电而被吸引。
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It's not like an ionic bond where atoms are attracted to each other because one is positive and the other is negative.
它甚至不像水中的氢键那样,分子的一部分略带正电,另一部分略带负电。
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It's not even a hydrogen bond like in water where part of the molecule is slightly positive and the other part is slightly negative.
不,壁虎依靠的是中性原子之间的吸引力。
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No, geckos rely on the attraction between neutral atoms.
那么它是如何工作的呢?
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So how does that work?
假设一只壁虎正在爬玻璃窗。
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Say a gecko is climbing up a glass window.
壁虎的原子是中性的,玻璃的原子也是中性的,但在任何特定瞬间,原子周围的电子并非完美均匀地分布在原子核周围。
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The gecko atoms are neutral and the glass atoms are neutral, but at any particular instant the electrons around in atom are not perfectly evenly distributed about the nucleus.
它们可能在一侧多一点,在另一侧少一点。
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They may be a little bit more on one side than the other.
这使得原子在一侧暂时带一点正电,在另一侧暂时带一点负电。
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And this makes the atom momentarily a little positively charged on one side and a little negatively charged on the other side.
现在,如果附近有一个非常近的原子,比如玻璃的一个原子在几纳米之内,这种电荷就能在玻璃原子上引起互补的电荷不平衡。
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Now if there's a neighboring atom really close to it, say an atom for the glass is within a few nanometers, this charge can induce a complimentary charge imbalance on the glass atom.
所以现在玻璃原子的电子被壁虎原子的原子核吸引,反之亦然。
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So now the electrons from the glass atom are attracted to the nucleus of the gecko atom and vice versa.
壁虎和玻璃之间存在一种非常微弱的吸引力。
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There is a very weak force of attraction between gecko and glass.
这被称为范德华力(Van der Waal's Force: 中性分子或原子之间的一种微弱的短程吸引力)。
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And this is known as a Van der Waal's Force.
范德华力至少部分解释了为什么量块(gauge blocks: 表面极其平滑的精密钢块)能粘在一起。
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Van der Waal's Forces are, at least in part, why gauge blocks, smooth flat pieces of steel, can stick together.
Mark: 它一直都在。
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It's there all the time.
如果你有一辆车,你知道,你可以在后窗上贴上这些乙烯基薄片,这样你的孩子在汽车座椅上就不会受到过多的阳光照射。
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If you have a car with, you know, you can put these vinyl sheets on the back window so that your kids don't get like excessive sun when they're in the car seat.
那也是范德华力。
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That's also Van der Waal's Force.
Derek: 但通常我们不会注意到范德华力。
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But generally we don't notice Van der Waal's Forces.
我们用手指感觉不到它们,因为至少在分子尺度上,我们的皮肤非常凹凸不平。
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We don't feel them with our fingers because at least on the molecular scale, our skin is incredibly bumpy.
触摸一块玻璃就像把山脉放在一个平面上。
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Touching a piece of glass is like putting a mountain range on top of a flat plane.
没有多少紧密接触点。
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There aren't many points of close contact.
壁虎通过所有那些微小的分支克服了这一点。
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Geckos overcome this using all those tiny branches.
Mark: 这意味着当壁虎放下脚时,它有一个非常大且紧密的接触面积。
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So this means that when the gecko puts its foot down, it has a very large intimate area of contact
这几乎就像你在表面上倒胶水,让它流淌一样。
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It's almost as if you were pouring glue on the surface and letting it flow.
这就是附着力发挥作用的原因。
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And that's what makes the adhesion work.
人工壁虎粘合剂的制造与机制
Derek: 复制壁虎复杂的支状结构目前是不可能的。
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Replicating the gecko's intricate branching structures is currently impossible.
Mark: 我们无法制造出壁虎拥有的东西。
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We cannot make what the gecko has.
我们做不到。
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We can't.
Derek: 那个结构,那个非常精细的支状结构。
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That structure, that really fine branching structure.
Mark: 那个复杂的支状结构。
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That sophisticated branching structure.
但我们可以做出一个更粗略的近似。
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but we can make a more crude approximation.
Derek: 在显微镜下,你可以看到人工壁虎粘合剂表面覆盖着一排排尖锐的楔形结构。
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Under a microscope, you can see that the artificial gecko adhesive is covered in rows of sharp wedges.
尖端大约一到两微米宽,比人类头发细一百倍。
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The tips are around one or two micrometers wide. That's a hundred times narrower than a human hair.
要制造出如此精细的结构需要一个劳动密集型的过程。
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To create such fine structures requires a labor-intensive process.
一块蜡被用作模具的基底,然后用剃刀片反复压入蜡块,形成楔形凹痕。
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A block of wax is used as the base for a mold and then a razor blade is repeatedly pressed into the block creating wedge-shaped indents.
硅酮聚合物(silicone polymer)被倒入模具中,并附着上背衬材料。
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A silicone polymer is poured into the mold and a backing material is attached.
Derek: 这是硅酮吗?
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This is silicone?
Lab Worker: 所以它叫Sylgard 170(一种硅酮聚合物),是的,它是一种硅酮。
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So it's called Sylgard 170. And it is a type of silicone, yes.
Derek: 大约24小时后,粘合剂固化并准备就绪。
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And after about 24 hours, the adhesive is cured and ready to go.
这就是它的样子。
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And that's what it looks like.
但模具只能使用几次,之后粘合剂的质量就会下降,你必须重新开始。
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But the mold can only be used a few times before the quality of the adhesive declines and you have to start all over again.
Mark: 这种尖锐的楔形结构具有一个有趣的特性,当你第一次将其接触表面时,唯一接触的部分是这些尖端。
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This sharp wedge structure, which has this interesting property that when you first bring it up to a surface, the only part in contact is these tips.
因此它不粘,因为没有值得一提的范德华力。
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So therefore it's not sticky because there's no Van der Waal's Force worth mentioning.
当你施加剪切力(shear force: 平行于物体表面作用的力)时,这些东西都会弯曲,我们就会得到一个更大,实际上几乎连续的接触面积。
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As you load it in shear, these things all bend over and we get a much larger, in fact almost continuous contact area.
所以就像壁虎一样,我们有一些范德华力可以利用,这就是我们获得附着力的原因。
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And so like the gecko, we have some Van der Waal's Forces to work with and that's what give us adhesion.
Derek: 所以要让粘合剂粘住,你必须平行于表面拉动它,这被称为剪切力,并且你必须朝能使楔形结构弯曲的方向拉动,以便它们与表面接触。
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So to make the adhesive stick you have to pull it parallel to the surface, that's known as a shear force, and you have to pull it in the direction that will bend the wedges so that they make contact with the surface.
如果你朝任何其他方向拉动,它就不会粘住。
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If you pull it in any other direction, it won't stick.
这使得将粘合剂直接从表面拉开变得容易。
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This makes it easy to pull the adhesive straight off the surface.
我的意思是,基本上没有接触力。
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I mean, there is basically no contact force.
Lab Worker: 所以我们清洁它的方法就是用胶带,因为胶带不粘Sylgard,但灰尘颗粒会粘上去。
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And so the way we clean this is just with tape, because tape doesn't stick to the Sylgard, but the dust particles do.
仿生粘合剂的广泛应用
Derek: 他们利用这一特性创造了一种极其微小轻巧的机器人,名为MicroTug(微型牵引机器人)。
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They used this property to create an incredibly small and lightweight robot called MicroTug.
它仅重17克,却能拉动20公斤的重量。
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It weighs just 17 grams, but is able to pull a 20 kilogram weight.
这相当于一个人拖动一头蓝鲸。
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That's the equivalent of a human towing a blue whale.
仅仅六个这样的微型机器人就能拖动一辆汽车。
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Just six of these tiny robots can tow a car.
壁虎粘合剂位于MicroTugs的底部。
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The gecko adhesive is on the underside of the MicroTugs.
所以当它们拉动汽车时,材料处于剪切状态,并紧紧粘在地面上。
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So when they're pulling the car, the material is in shear and it sticks tight to the ground.
但随着汽车向前移动,剪切力减小,因此机器人很容易抬起自身并向前移动。
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But as the car moves forward, the shear force decreases and so it's easy for the robot to pick itself up and move itself forward.
可达到的拉力大小取决于粘合剂与表面接触的面积。
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The amount of pulling force attainable depends on the area of adhesive that's in contact with the surface.
因此他们开发了一种通过光线穿透亚克力来测量接触面积的方法。
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So they've developed a method for measuring this by shining light through acrylic.
Tony: 所以它的作用是让LED光线穿过亚克力,每当与表面接触时,它就会阻碍光线,并精确显示接触区域在哪里。
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So what it does is shines the LED across the acrylic and whenever there's a contact with the surface, it frustrates the ray and it shows you exactly where the contact area is.
Derek: 一平方英寸的接触面积可以支撑大约4.5公斤或10磅的重量。
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One square inch of contact area can support the weight of about four-and-a-half kilograms or 10 pounds.
由于粘合剂是定向的,为了抓取物体,两块粘合剂会以相反的方向附着。
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Since the adhesive is directional, to grip an object two pieces of adhesive are attached in opposite directions.
所以当你向上拉时,两边都处于剪切状态,因此它们都粘住。
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So when you pull up, both sides are in shear and so they both stick.
两块相对的粘合垫实际上在国际空间站的一个机器人上进行了测试。
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Two opposing pads of adhesive were actually tested on a robot on the international space station.
Mark: 它叫Astrobee(国际空间站上的自由飞行机器人)。
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It's called Astrobee.
把它想象成一架无人机,一个无人飞行器,只是它实际上使用风扇在国际空间站内部推动自己移动。
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Think of it as like a drone, a UAV, only actually uses a fan to push itself around inside the International Space Station.
其想法是它可以用来拍摄视频或为宇航员取东西。
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And the idea is that it could be there to take video or fetch something for astronauts.
我们的建议是:“它能不能轻轻地漂浮并粘在墙上,例如,或者拿起一个大箱子?”
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Our proposal was, "How about it should be able to float along gently and stick itself to a wall, for example. Or pick up a big box.
Astronaut: 我们的目标是让那个蓝色LED变成绿色。
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Our goal is to get that blue LED to turn green
Mark: 因为没有重力,你实际上不需要很大的力,但你确实希望能够非常轻柔地抓取并轻松释放。
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Because there's no gravity. You don't actually need a lot of force but you do want to be able to grab very gently and and release easily.
所以我们把壁虎粘合剂带到了国际空间站,它在那里工作得和在这里一样好。
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And so we got the gecko adhesives up at International Space Station and it works just as well up there as it does down here.
Derek: 这个去了太空,在空间站里?
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This went to space, this was in the space station?
Mark: 这个在空间站里待了大约一年半。
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This was in Space station for about a year-and-a-half.
Derek: 哇。
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Wow.
这个原理可以扩展到三块粘合剂,这样当你把它们都拉进去时,它们就能粘在平面上。
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This principle can be extended to three pieces of adhesive so that when you pull them all in they can stick to a flat surface.
当它静止时,这些东西会稍微突出一点,然后当你拉动时,它们就会变得更平,对吗?
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When it's at rest, these things are sticking up just a little bit and then when you pull there, then they become flatter right?
Tony: 是的,整个垫子不会完全接触,因为两个表面都不是完全平坦的。
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Yeah, the entire pad doesn't touch because it's both surfaces is not perfectly flat.
然后一旦你激活它。
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And then once you activate it.
Derek: 哦,是的,我完全能看出来。
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Oh yeah, I could totally see that.
Tony: 所以我要拔掉电源,这样它就完全没有电了,但它仍然附着在表面上。
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So I'm going to unplug the power so there's absolutely no power to it at all and it's still attach the surface.
Derek: 是的,我以为你必须保持电机开启,但它只是锁定了位置还是怎么回事?
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Yeah, I was thinking that you'd have to keep the motor on but it just sort of like locks in position or what?
Tony: 是的,只要有一点点张力,它就会永远保持在那里。
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Yeah, as long as there's tiny bit of tension it just stays there forever.
Derek: 这种材料有很多潜在的应用,但最明显的是用于机器人抓手。
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There are lots of potential applications for this material, but the most obvious one is for robotic grippers.
由于粘合剂只需很小的剪切力就能很好地粘附,因此非常适合抓取农产品等精致物品。
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Since the adhesive sticks well with just a small shear force, it's great for picking up delicate items like produce.
Mark: 这些基本上是智能壁虎手掌。
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These are meant to be smart gecko palms, basically.
所以我们尝试以最小的挤压进行抓取。
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So we're trying to grasp with minimal squeezing.
Lab Worker: 我们甚至没有真正启动棘轮机制。
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We're not even really engaging the ratchet mechanism there.
Mark: 是的,完全没有。
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Yeah, not at all.
所以它小于一牛顿。
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So it's like less than a Newton.
它还可以抓取大件物品或抓住一个篮球。
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It can also grab bulky items or palm a basketball.
那么壁虎粘合剂能拉动汽车吗?
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Now can the gecko adhesive pull a car?
他们把这个连接到这根绳子上,绳子又连接到这里的绞盘上,但绞盘实际上没有固定。
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They have hooked this one up to this rope, which is connected to a winch here, but the winch is not actually secured.
它被四块壁虎粘合剂系在管道上。
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It is tethered back to four pieces of gecko adhesive which are just sitting on this pipe.
所以问题是,这四块壁虎粘合剂能否在绞盘拉动汽车时将其固定住?
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So the question is, can these four pieces of gecko adhesive anchor the winch as it pulls that car back?
(绞盘发出研磨声)
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(winch grinding)
哦,是的,它在动。
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Oh yeah, it's moving.
(绞盘发出研磨声)
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(winch grinding)
哇。
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Wow.
我能把这些拉下来吗?
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Could I pull these off?
All: 是的,可以。
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Yep, yeah.
Derek: 有多少……好像什么都没把它固定住。
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How much does... like there was nothing holding it on.
这太疯狂了。
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That's wild.
但当然,每个人都想要的应用是能够攀爬建筑物。
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But of course the application everyone wants is to be able to climb a building.
这实际上是研究生埃利奥特·霍克斯(Elliot Hawks)的一个博士项目。
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And this was actually a PhD project for grad student Elliot Hawks.
这是一个挑战,因为他必须在任何时候让足够的壁虎粘合剂与玻璃接触,以支撑他的全部体重。
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It was a challenge because he had to get enough gecko adhesive in contact with the glass at any one time to support his whole weight.
如果你想让我尝试用壁虎粘合剂爬建筑物,甚至爬得更快一点,请告诉我。
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Let me know if you want me to try to climb a building with gecko adhesive and maybe even go a little bit faster.
(电子蜂鸣声)
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(electronic beeping)
赞助商信息:Brilliant在线学习平台
嘿,本视频由Brilliant(一个在线学习工具)赞助,它能帮助你理解改变游戏规则的技术。
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Hey, this video was sponsored by Brilliant, the online learning tool that helps you understand game-changing technologies.
不仅在物理科学领域,还在计算机科学领域。
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Not only in the physical sciences, but also in computer science.
你知道,现在每个人都在谈论神经网络(neural networks: 模仿人脑结构和功能的计算模型)。
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You know, these days everyone's talking about neural networks.
人工智能如何赢得任何游戏或用ChatGPT(由OpenAI开发的大型语言模型)写十四行诗。
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How AI can win any game or write sonnets with ChatGPT.
这样的技术已经在改变世界,你真的应该了解它是如何运作的。
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Tech like this is already changing the world and you should really know how it works.
Brilliant有深入探讨神经网络内部机制的课程,以发现计算机系统如何真正学习。
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Brilliant has courses that delve into the inner machinery of neural networks to discover how a computer system can actually learn.
你将能够应用所学知识,并自己构建一个神经网络来识别数字、形状和物体。
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You'll be able to apply what you've learned and build a neural network yourself to recognize numbers, shapes, and objects.
如果你需要先复习数学或计算机科学技能,Brilliant拥有一个完整的课程库,从初级到中级再到高级。
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And if you need to refresh your math or computer science skills first, Brilliant has a whole library of courses, ranging from beginner to intermediate to advanced.
就我个人而言,我把Brilliant当作一个“思维健身房”。
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Personally, I use Brilliant as a mental gym.
前几天我正在学习群论(group theory: 数学的一个分支,研究群的代数结构)的一课,Brilliant比任何其他平台做得更好的一点是,它迫使你独立思考。
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The other day I was going through a lesson on group theory, and the thing Brilliant does better than any other platform is it forces you to think for yourself.
它在每一步都会向你提问,而且材料经过精心策划,随着你的学习进程,复杂性会逐渐增加。
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It asks you questions every step of the way and the material is carefully curated to increase in complexity as you go.
我发现自己解决问题真的很有成就感。
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I find it really satisfying to work things out for myself.
那是真正理解某件事的唯一方法。
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That's the only way to truly understand something.
你可以通过访问brilliant.org/veritasium免费试用Brilliant。
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And you can try Brilliant out for free by going to brilliant.org/veritasium.
如果你想订阅年度高级会员,前200名通过该链接加入的人可以获得20%的折扣。
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And if you want to sign up for an annual premium subscription, the first 200 people to join get 20% off through that link.
所以我会把它放在描述中。
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So I will put it down in the description.
我要感谢Brilliant对Veritasium的支持,也要感谢你的观看。
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I want to thank Brilliant for supporting Veritasium and I want to thank you for watching.