意外发现反物质之人:保罗·狄拉克与量子物理的革命 Veritasium 2025-12-05

狄拉克方程的诞生与量子物理的震动

1928年,一位年轻人在德国的讲台上发表了他近期工作的演讲。他有着一种略显不同寻常的演讲风格。物理学家尤金·维格纳(Eugene Wigner: 匈牙利裔美国理论物理学家,诺贝尔物理学奖得主)形容那次演讲是超然的,几乎就像是在背诵一篇技术文本。他说:“这个人说话时,没有表现出任何享受自己演讲的迹象。”然而,这位奇怪而谦逊的年轻人所展示的工作,即将让20世纪一些最著名的量子物理学家(Quantum Physicists: 研究量子力学及其应用的科学家)陷入困惑。

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In 1928, a young man shuffled onto a stage in Germany to present a lecture on his recent work. He had a slightly unusual presentation style. Physicist Eugene Wigner described the lecture as detached, almost like a recitation of a technical text. He said, "The man spoke without giving any sign of enjoying his own lecture." But the work this strange unassuming man presented was about to send some of the most famous quantum physicists of the 20th century spiraling. (suspenseful music)

演讲结束后,维尔纳·海森堡(Werner Heisenberg: 德国理论物理学家,量子力学的创始人之一,诺贝尔物理学奖得主)将这个人的理论描述为“现代物理学中最悲伤的一章”。海森堡还写信给尼尔斯·玻尔(Niels Bohr: 丹麦物理学家,量子力学和原子结构理论的先驱,诺贝尔物理学奖得主)说:“我发现目前的局面相当荒谬,因此,几乎绝望地,我已转向另一个领域。”传说沃尔夫冈·泡利(Wolfgang Pauli: 奥地利理论物理学家,量子力学的先驱之一,泡利不相容原理的提出者)甚至宣布他要放弃量子物理学,然后开始写一本乌托邦小说。这位年轻人究竟说了什么,竟如此深刻地颠覆了量子力学(Quantum Mechanics: 描述原子和亚原子粒子行为的物理学理论)的世界?他一直在研究一个物理学家至今仍在努力解决的问题:爱因斯坦(Albert Einstein: 德裔美国理论物理学家,相对论的创始人)相对论(Relativity: 描述空间、时间、引力与运动之间关系的物理理论)与量子力学的统一。而他的工作揭示了一些令人不安的东西——一种前所未见的粒子,一种具有负能量(Negative Energy: 理论上能量值小于零的状态)的粒子。

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After the lecture, Werner Heisenberg described the man's theory as, "The saddest chapter in modern physics." Heisenberg also wrote to Niels Bohr and said, "I find the present situation quite absurd and, on that account, almost out of despair, I have taken up another field." Legend has it that Wolfgang Pauli even announced that he was abandoning quantum physics, and then he started writing a utopian novel. What had the young man said to disrupt the world of quantum mechanics so profoundly? But he had been working on a problem that physicists are still tackling today. The unification of Einstein's relativity and quantum mechanics, and his work had revealed something troubling, a particle unlike any scene in the world, a particle with negative energy. (suspenseful music)

爱因斯坦的狭义相对论与E=mc²

1905年,阿尔伯特·爱因斯坦发表了他的狭义相对论(Special Theory of Relativity: 爱因斯坦提出的关于时空和运动的理论,适用于惯性参考系)。它基于一个简单的思想:对于任何以恒定速度运动的人来说,物理定律应该都是相同的,这包括对光速的任何测量。所以,无论你相对于一束光如何运动,你测量的光速都应该是每秒3亿米。这意味着我们通常认为固定不变的事物,比如时间和空间,必须发生转变,以便光速总是被测量出相同的值。在做出这一发现时,爱因斯坦意识到空间和时间根本不是真正独立的维度。它们在一个被称为时空(Spacetime: 相对论中将空间和时间结合起来的四维结构)的四维结构中相互关联。

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In 1905, Albert Einstein published his special theory of relativity. It was based on the simple idea that for anyone moving with constant speed, the laws of physics should be the same, and this includes any measurement of the speed of light. So, it doesn't matter how you're moving relative to a beam of light, you should measure its speed to be 300 million meters per second. This means that things that we ordinarily think of as fixed, like time and space, have to transform, so that the speed of light is always measured to have the same value. In making this discovery, Einstein realized that space and time are not really separate dimensions at all. They're linked in a four-dimensional fabric called spacetime. (pensive music)

当爱因斯坦将这个想法应用于一个发光的物体时,他发现了一些奇特之处。当一个物体通过发射光子(Photons: 光的基本粒子,电磁辐射的量子)失去能量时,它的质量也必须减少,并且物体质量的变化等于发射光子的能量除以光速的平方。换句话说,他发现能量必须等于mc²。E=mc²。

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When Einstein applied this idea to an object emitting light, he found something peculiar. When an object loses energy by emitting photons, its mass must also decrease, and the change in the object's mass is equal to the energy of the photons emitted divided by the speed of light squared. In other words, he found that energy must be equal to mc squared. E equals mc squared.

爱因斯坦说:“质量和能量不过是同一事物的不同表现。”因此,一个粒子的总能量来自它的动量(Momentum: 质量与速度的乘积,衡量物体运动的量)和它的静止质量(Rest Mass: 物体在静止时的质量),这赋予了能量和动量之间的新关系。现在,如果我们对两边取平方根,我们就可以得到一个粒子能量的表达式,它由粒子的质量和动量表示。如果我们在一维空间中绘制能量与动量的关系曲线,我们就会得到这条曲线,其中mc²,即物体的静止质量能量,是能量的最低可能值。但实际上,当我们取平方根时,我们应该在前面加上一个正负号,这将给我们两条曲线:一条用于正能量,另一条用于负能量。但我们没有观察到能量小于0的事物。我的意思是,那会意味着什么呢?

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- [Einstein] Mass and energy are but different manifestations of the same thing. - So, a particle's total energy comes from its momentum and its rest mass, giving it new relationship between energy and momentum. (pensive music) Now, if we take the square root of both sides, we get an expression for the energy of a particle in terms of its mass and momentum. And if we plot energy versus momentum in a single dimension, we get this curve, where mc squared, the rest mass energy of the object, is the lowest possible value for energy. But really, when we took the square root, we should have put a plus/minus out front, which would give us two curves: one for positive energies and another for negative energies. But we don't observe things that have energy less than 0. I mean, what would that even mean?

所以在经典物理学(Classical Physics: 19世纪末以前发展的物理学理论,不包括量子力学和相对论)中,解决方案很简单。你只需忽略负能量解。它们在物理上不可能代表任何东西,对吗,卡斯珀?

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So, in classical physics, the solution is simple. You just ignore the negative energy solutions. They can't physically represent anything, right, Casper?

卡斯珀说:“嗯,听起来是这样。但就在爱因斯坦提出他的狭义相对论的同时,物理学家们开始在原子物理学(Atomic Physics: 研究原子结构和性质的物理学分支)中观察到一些奇怪的现象,这些现象正在推翻所有这些经典假设。”首先,他们注意到在观察亚原子粒子(Subatomic Particles: 比原子更小的粒子,如电子、质子、中子)的能级时,比如电子(Electrons: 带负电荷的亚原子粒子),它们根本不是连续的,而是离散的。而且它们不仅表现为粒子,还表现为波。所以,如果你取电子并通过两个狭缝发射它们,那么它们就会产生干涉图样(Interference Patterns: 当两列或多列波叠加时形成的图案),就像光一样。他们正在发现的是量子力学的新领域。

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- Well, sure, that sounds right. But around the same time that Einstein was coming up with his special theory of relativity, physicists began observing some strange phenomena in atomic physics that were overthrowing all of these classical assumptions. First of all, they noticed that when looking at the energy levels of subatomic particles, like electrons, they weren't continuous at all, they were discrete. And they also didn't just behave as particles, but as waves. So, if you would take electrons and fire them through two narrow slits, then they would create interference patterns, just like light does. What they were discovering was the new field of quantum mechanics. (suspenseful music)

薛定谔方程的局限性

1926年,埃尔温·薛定谔(Erwin Schrodinger: 奥地利物理学家,量子力学的创始人之一,薛定谔方程的提出者)通过提出他现在著名的波方程(Wave Equation: 描述波如何随时间演化的偏微分方程),使这个领域正式化,该方程描述了量子力学系统如何随时间演化。

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And in 1926, Erwin Schrodinger formalized this field by coming up with his now-famous wave equation, which describes how quantum mechanical systems evolve over time.

“这是20世纪最激进的新理论,并将一直如此。这与牛顿或麦克斯韦的理论完全不同。这是彻底的创新。”卡斯珀说,这个方程的解,被称为波函数(Wave Function: 量子力学中描述粒子量子态的数学函数,其模的平方表示粒子在某处出现的概率),psi,并不像经典定律那样描述具有精确位置和动量的粒子。相反,其模的平方可以给出在特定时间在特定位置找到粒子的概率。

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- This was the most radical new theory of the 20th century, and would remain so. This is not a bit like Newton or a bit like Maxwell. This was radically new. - [Casper] The equation solution, called the wave function, psi, does not describe a particle with a precise position and momentum as classical laws would. But instead, the modular squared can give us the probability of finding the particle in a specific location at a specific time.

推导薛定谔方程(Schrödinger Equation: 描述量子力学系统中波函数如何随时间演化的方程)实际上出奇地简单。只需写下总能量,对于一个自由粒子来说,它就是它的动能(Kinetic Energy: 物体因运动而拥有的能量),½mv²。我们可以用动量(质量乘以速度)来重新写它。所以动能就是动量平方除以2m。现在,我们要把它量子化,为此我们需要两样东西。第一个是波函数psi,它描述了粒子在量子尺度上如何表现为波。第二个是被称为量子算符(Quantum Operator: 量子力学中用于提取波函数信息的数学工具,对应可观测物理量)的东西。这只是一个数学工具,它从波函数中提取信息以揭示粒子的特定属性,比如它的位置、能量或动量。能量和动量的算符看起来像这样。通过输入这些算符,我们可以使方程的两边作用于波函数,这就得到了自由粒子的薛定谔方程。

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- Deriving the Schrodinger equation is actually surprisingly simple. Just start by writing down the total energy, which, for a free particle, is just its kinetic energy, 1/2 mv squared. And we can rewrite it in terms of momentum, mass times velocity. So kinetic energy is just momentum squared divided by 2m. Now, we're going to make this quantum, and to do that, we need two things. The first is the wave function, psi, which describes how particles act as waves at quantum scales. And the second is something called a quantum operator. This is just a mathematical tool that extracts information from the wave function to reveal a specific property of the particle, like its position, energy, or momentum. The operators for energy and momentum look like this. By inputting these operators, we can make each side of the equation act on the wave function, and that gives us the Schrodinger equation for a free particle. (pensive music)

对于非自由粒子,比如原子中的电子,你还需要考虑势能(Potential Energy: 物体因其位置或状态而拥有的能量),这会得到完整的薛定谔方程。

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For particles that aren't free, like electrons in atoms, you need to factor in potential energy, too, which gives you the full Schrodinger equation. (pensive music)

但是,在某些情况下,它无法给出正确的预测。例如,以金元素为例。薛定谔方程表明它应该是银灰色,就像所有其他金属一样。但它不是,它是金色的。对于汞,薛定谔方程预测它在室温下应该是固体,但它是液体。那么,问题出在哪里?我会给你一个提示,因为金和汞都是重元素。

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- But there are some places where it doesn't produce the right prediction. For example, take the element gold. The Schrodinger equation suggests that it should be a silver gray color, just like all the other metals. But it's not, I mean, it's gold. And for mercury, the Schrodinger equation predicts that it should be a solid at room temperature, but it's a liquid. So, what is wrong? Well, I'll give you a hint, because both gold and mercury are heavy elements.

德里克说:“它们的原子核中含有大量的质子,这些质子更强烈地吸引着轨道电子。所以,如果你以经典的方式思考,电子会被更紧密地束缚在原子核内,它们会以比其他元素更高的速度旋转。对于某些轨道上的电子,这些速度开始接近光速。”

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- [Derek] They have a high number of protons in their nuclei, which attract orbiting electrons more strongly. So, if you're thinking in a classical sense, the electrons would be bound tighter in, and they'd be whizzing around at higher speeds than in other elements. And for electrons in some orbits, those speeds starts to get a little too close to the speed of light. (pensive music)

所以,让我们回到薛定谔方程。在那里,我们有动能是p²除以2m。但是对于以接近光速的相对论性速度(Relativistic Speeds: 接近光速的速度,此时相对论效应变得显著)运动的粒子,那个方程是不正确的。正确的方程是狭义相对论中的能量动量关系。

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So, let's go back to the Schrodinger equation. There, we had the kinetic energy was p squared over 2m. But for particles moving at relativistic speeds close to the speed of light, that equation isn't the right one. The correct equation is the energy momentum relation from special relativity.

“薛定谔方程与相对论不一致,所以它……从技术上讲,它是不正确的。”

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- Schrodinger's equation is not consistent with the theory of relativity, so it's... Technically, it's not right. (pensive music)

克莱因-戈登方程:第一次尝试

所以,解决方案看起来足够简单。只需从相对论能量动量关系开始,并用它来推导一个新的波方程。这正是物理学家奥斯卡·克莱因(Oskar Klein: 瑞典理论物理学家,克莱因-戈登方程的共同提出者)在1926年所做的。他代入了薛定谔使用的相同能量和动量算符,并得到了这个方程。

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- So, the solution seems simple enough. Just start with the relativistic energy momentum relation and use that to derive a new wave equation. (pensive music) Well, this is exactly what a physicist named Oskar Klein did in 1926. He subbed in the same energy and momentum operators that Schrodinger used, and found this equation. (pensive music)

克莱因的工作受到了他许多同事的好评。事实上,事实证明另外两位物理学家,沃尔特·戈登(Walter Gordon: 德国物理学家,克莱因-戈登方程的共同提出者)和弗拉基米尔·福克(Vladimir Fock: 苏联物理学家,克莱因-戈登方程的共同提出者),在同一年独立地得出了相同的方程。它被称为克莱因-戈登方程(Klein-Gordon Equation: 描述自旋为零的相对论性粒子的波方程),这对福克来说有点不公平。但事情往往就是这样。你做了所有的辛苦工作,然后没有人注意到。自福克时代以来,情况有所改变,但获得认可的关键仍然是知名度。如今,这意味着拥有一个网站。

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Klein's work was pretty well-received by a number of his colleagues. In fact, it turned out the two other physicists, Walter Gordon and Vladimir Fock, had independently arrived at the same equation in that same year. It became known as the Klein-Gordon equation, which was a bit of a burn for Fock. (graphic whooshing) (graphic twinkling)

这足够简单,你只需要编写几千行CSS、JavaScript或HTML,或者花几千美元请人为你做。哦,还有托管费用和维护。或者你可以看看今天的赞助商Hostinger。他们不仅能让你的网站上线,他们直观的工具还能让你自己构建网站。无需学习多种编码语言。Hostinger构建器只需一个提示就能让你完成大部分工作。你可以使用他们内置的工具优化网站,包括SEO评级、标志设计和电子商务。一旦你满意,你的网站就会立即上线,并且包含在套餐中的域名。整个过程快速而直接,订阅每月只需几美元。所以,现在注册即可享受85%的折扣,并在促销中使用代码VERITASIUM额外享受10%的折扣。只需扫描此二维码或点击描述中的链接即可开始。我要感谢Hostinger赞助视频的这一部分。

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But that's often how it goes. You do all the hard work and then no one notices. Things have changed a little since Fock's time, but the key to recognition is still visibility. And these days, that means having a website. Simple enough, you just need to write a couple thousand lines of CSS, JavaScript, or HTML, or else pay someone a few thousand dollars to do it for you. Oh, and then there's the hosting costs and the maintenance. Or you could check out today's sponsor, Hostinger. Not only will they get your website online, their intuitive tools let you build it yourself. There's no need to learn multiple coding languages. The Hostinger builder can get you most of the way there with just one prompt. You can optimize the website with their built-in tools for SEO rating, logo design, and e-commerce. And once you're happy, you're online immediately on a domain that's included with the plan. That whole process is fast and straightforward, and a subscription is just a few dollars a month. So, sign up now to get an 85% discount in the sale and use the code VERITASIUM for an extra 10% off. Just scan this QR code or follow the link in the description to get started. I wanna thank Hostinger for sponsoring this part of the video.

现在,回到克莱因、戈登和福克。克莱因-戈登-福克方程甚至传到了量子物理学之父之一尼尔斯·玻尔那里,他一定印象深刻,因为在1927年的索尔维会议上,玻尔正在与一位前途光明的年轻物理学家讨论他正在研究什么。这位年轻人说:“我正在尝试建立一个电子的相对论理论。”玻尔回答说:“但是克莱因已经解决了这个问题。”这位年轻人不同意。那么,这位大胆的25岁年轻人是谁?他就是保罗·狄拉克(Paul Dirac: 英国理论物理学家,量子力学和量子电动力学的奠基人之一,狄拉克方程的提出者),一个玻尔后来给他起了“最奇怪的人”绰号的人,因为他确实是独一无二的。

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And now, back to Klein, Gordon, and Fock. The Klein-Gordon-Fock equation even made its way over to one of the fathers of quantum physics, Niels Bohr, who must have been impressed, because at the 1927 Solvay Conference, Bohr was chatting to a promising young physicist about what he was working on. The young man said, "I'm trying to get a relativistic theory of the electron." Bohr replied, "But Klein has already solved this problem." The young man disagreed. So, who was this bold 25-year-old? He was Paul Dirac, a man who Bohr would later give the nickname The Strangest Man because he was truly one of a kind.

“我第一次去普林斯顿的时候,遇到了一对夫妇,他们邀请了狄拉克和他的妻子。狄拉克在整个用餐过程中,持续了三个小时,一句话也没说。一个字也没有。他没有闷闷不乐,也没有生气。他只是觉得没有理由说话。”

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- First time I went to Princeton, I met a couple who invited Dirac and his wife. And Dirac, for the whole meal, which lasted three hours, didn't say a single word. Not one word. He wasn't sulky, he wasn't angry. He just saw no reason to speak.

“那太疯狂了。”德里克说:“狄拉克是一个话很少的人,他的同事们甚至发明了一个特殊的单位,一个‘狄拉克’,相当于每小时说一个字。传说他还喜欢穿着三件套爬树来放松。那不是他唯一的奇怪爱好。作为一名学生,狄拉克参加了爱因斯坦相对论的研讨会,他有点爱上了它。他被其数学的优雅和美丽所打动。对狄拉克来说,这触及了一个好理论必须做的核心。他曾说:‘方程的美比它们符合实验更重要。’”

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- That's crazy. - [Derek] Dirac was a man of so few words that his colleagues invented a special unit, a Dirac, equivalent to speaking one word per hour. Legend also has it that he liked to relax by climbing trees in three-piece suits. And that wasn't his only strange hobby. As a student, Dirac had attended seminars on Einstein's theory of relativity, and he'd kind of fallen in love with it. He was impressed by the elegance and beauty of its mathematics. To Dirac, this got to the core of what a good theory must do. He once said, "It is more important to have beauty in one's equations than to have them fit experiment." (pensive music)

卡斯珀问:“你知道狄拉克为什么如此被相对论吸引吗?”“爱因斯坦进去做了所有……不是所有,但几乎所有都是通过演绎推理完成的。这给狄拉克留下了深刻的印象,对吧?他意识到先进的数学对于理解自然运作方式非常重要。”

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- [Casper] Do you know why Dirac was so drawn to relativity? - Einstein went in there and did it all... Not all, but almost all by deductive reasoning. That made a huge impression on Dirac, right? He realized that it was advanced mathematics was really important to understanding the way that nature works.

所以,狄拉克找到了一个新爱好,痴迷地用爱因斯坦的相对论更新经典方程,以便它们现在也适用于接近光速的相对论物理场景。他后来表示这对他来说就像一场游戏,所以他成为试图统一量子物理学和相对论的人之一,也许并不令人惊讶,因为一个能涵盖这两者的理论在他看来将是真正美丽的。

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- So, Dirac found a new hobby, obsessively updating classical equations with Einstein's theory of relativity, so that they would now work for relative physics scenarios as well that are those approaching the speed of light. He later said this was like a game for him, and so it's maybe not too much of a surprise then that he was one of the people trying to unite quantum physics and relativity because a theory that would cover both of these would be truly beautiful in his eyes.

狄拉克在克莱因、戈登和福克对薛定谔方程的相对论更新中没有看到美,他也不是唯一一个。物理学家沃尔夫冈·泡利在阅读了克莱因的论文后,给他写了一封信,祝他的物理学早日康复。泡利以刻薄著称。实际上,克莱因-戈登方程在某些情况下是有用的,但他和狄拉克都关注该方程的一个特定特征。

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- Dirac didn't see the beauty in Klein, Gordon, and Fock's relativistic update of the Schrodinger equation, and he wasn't alone. Fellow physicist, Wolfgang Pauli, after reading Klein's paper, wrote him a letter, wishing his physics a speedy recovery. Pauli was known for being pretty savage. And actually, the Klein-Gordon equation is useful in some cases, but he and Dirac were both concerned with one particular feature of the equation.

那是因为克莱因-戈登方程包含这个项,它是一个二阶时间导数(Second-Order Time Derivative: 物理量对时间求两次导数,通常表示加速度或变化率的变化)。所以波函数对时间进行了两次微分。现在,请记住,薛定谔方程也包含一个二阶导数,但那是对空间求导,而不是对时间求导。时间只是一阶导数(First-Order Derivative: 物理量对时间求一次导数,通常表示速度或变化率)。那么,为什么这是一个问题呢?

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- And that's because the Klein-Gordon equation contains this term. That's a second-order time derivative. So the wave function is being differentiated twice with respect to time. Now, remember, the Schrodinger equation also contains a second-order derivative, but that's with space, not with time. Time is just first-order. So, why is this such a problem?

想想一个非常简单的二阶时间导数。比如d²y/dt²等于3。现在,要找出y是什么,即满足这个方程的函数,我们只需对其积分两次。但请注意,要找到解,我们现在需要两个积分常数c和D。问题是,我们只有在知道给定时间y的值和给定时间y的一阶导数时才能找到它们。这在物理上是有意义的,如果你考虑,比如说,把一个球扔到空中。如果你想预测球未来的运动,那么你需要知道你从哪里扔的,那是它的位置,以及你扔得多用力,那是它的速度。换句话说,你需要知道位置和位置的一阶导数。

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Well, think of a very simple second-order time derivative. Something like d squared y over dt squared is equal to 3. Now, to figure out what y is, the function that satisfies this equation, we just have to integrate it twice. (pensive music) (record scratching) But notice, to find the solution, we now two integration constants, c and D. And the problem is that we can only find that if we know both y at a given time and if we know the first derivative of y at a given time. This makes sense physically, if you think about, say, throwing a ball in the air. If you want to predict the ball's future motion, well, then, you need to know where you threw it from, that's its position, and how hard you threw it, that's its velocity. Or in other words, you need to know both the position and the first derivative of the position. (suspenseful music)

同样,要使用克莱因-戈登方程预测量子系统的未来状态,你需要初始波函数和波函数的初始一阶导数。

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- Similarly, to predict a quantum systems future state using the Klein-Gordon equation, you'd need the initial wave function and the initial first derivative of the wave function. (suspenseful music)

现在,薛定谔方程的美妙之处在于,如果你只知道系统在给定时间的波函数,你就可以用它来确定该系统的所有未来状态。但在克莱因-戈登方程中,波函数不再能说明全部情况。这又引入了一个问题。在给定区域找到粒子的概率不再能简单地用波函数的模量(Modulus of the Wave Function: 波函数的绝对值,其平方表示概率密度)来描述,就像薛定谔方程那样。对于克莱因-戈登方程,需要一个新的方程来使用波函数描述概率,这需要一段时间来推导,所以我们在这里不深入讨论,但它看起来像这样。而那个方程的问题在于,与波函数的简单模量不同,它可以有负解,即负概率。事情发生的几率怎么可能小于零呢?正如狄拉克所说,那当然在物理上是荒谬的。

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Now, the beauty of the Schrodinger equation was that if you knew only the wave function of a system at a given time, you could use it to determine all the future states of that system. But in the Klein-Gordon equation, the wave function no longer told the whole story. And this introduced a further problem. The probability of finding a particle in a given area could no longer be simply described by the modulus of the wave function, as it was for the Schrodinger equation. For the Klein-Gordon equation, a new equation was needed to describe the probability using the wave function, which takes a while to derive, so we won't get into that here, but it looks like this. And the problem with that equation is that unlike the simple modulus of the wave function, it can have negative solutions, negative probabilities. How can the chance of something happening be less than zero? As Dirac put it, that, of course, is physically nonsense. (suspenseful music)

狄拉克的灵光一现:矩阵与狄拉克方程

所以,狄拉克做了他最擅长的事情,他着手寻找自己的解决方案,其中不包含二阶时间导数。首先,他将相对论能量动量关系改写成这样,这是一个线性方程。所以没有对E求平方,也就是说没有对能量算符求平方,而这正是克莱因-戈登方程中产生二阶时间导数的原因。现在,他只需要解这个方程,找到系数alpha xalpha yalpha zbeta,他就能得到一个解。

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So, Dirac did what Dirac does best, and he set out to find his own solution that contained no second-order time derivatives. First, he rewrote the relativistic energy momentum relationship like this, which is a linear equation. So no squaring E, that is no squaring the energy operator, which is what gave rise to that second-order time derivative in the Klein-Gordon equation. Now, he just had to solve this equation and find the coefficients, alpha x, alpha y, alpha z, and beta, and he would have a solution. (pensive music)

为了做到这一点,我们可以从方程两边同时平方开始。接下来,我们可以将左侧的动量展开成三个维度,然后展开右侧,最终得到这个长方程。它可能看起来很复杂,但我们可以使用一个技巧。请注意,右侧的所有这些项都乘以pmc³,但左侧没有包含pmc³的项。这告诉我们,当你将这些系数相乘时,比如alpha乘以betabeta乘以alpha,所有这些都必须是0。同样,请注意,这些项乘以两个不同的动量,比如pxpy乘以c²,它们在左侧也没有对应项。所以这些alpha乘以alpha的项也必须等于0。这样就只剩下最上面一行了。这些项在两边都匹配,这告诉我们alpha x的平方必须等于1,alpha y的平方、alpha z的平方和beta的平方也必须等于1。所以狄拉克现在有了一组关于alpha xalpha yalpha zbeta的联立方程,他只需要解它们。听起来很简单,对吧?但它没那么简单。

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To do this, we can start by squaring both sides of the equation. Next, we can expand the momentum on the left-hand side into its three dimensions, and then expand the right-hand side to end up with this long equation. It might look pretty complicated, but there is a trick we can use. (pensive music) And notice that all these terms on the right-hand side are multiplied by pmc cubed, but on the left-hand side, there are no terms containing pmc cubed. So that tells us that when you multiply these coefficients together, like the alpha times beta and beta times alphas, all of that must be 0. And similarly, notice that these terms are multiplied by two different momenta, like px and py times c squared, which also don't have a counterpart on the left-hand side. So these alpha times alpha terms must also be equal to 0. And that just leaves this top row. These terms do match on both sides, which tells us that alpha x squared must be equal to 1, and so must alpha y squared, alpha z squared, and beta squared. So Dirac now had a set of simultaneous equations for alpha x, alpha y, alpha z, and beta that he just needed to solve. That sounds easy, right?

“要明白为什么,我们来做一些例子。假设alpha x是1,beta是-1。那么,我们得到1的平方是1,等于-1的平方也是1,所以这满足了上面的方程。但如果我们把它代入这里,我们得到1乘以-1,结果是-1,加上-1乘以1,结果又是-1,总共是-2。所以,这行不通。那么,我们再试一个数字。假设alpha x是1,现在alpha z是-1。那么在这种情况下,我们得到1乘以-1。所以,我们再次得到-1,加上-1乘以1,再次是-1。所以我们再次得到-2。事实上,如果你看这个上面的方程,唯一满足这个关系的数字是1和-1。所以所有这些系数都必须是1或-1,但如果你代入,那么你在这些方程中得到的唯二可能答案是-2或+2。现在,导致问题的两个方程是这两个,那是因为alpha乘以betabeta乘以alpha是相同的。所以,你总是会得到-2或2。所以,摆脱这种情况的唯一方法是设法让乘法的顺序变得重要。但你在哪里能找到这样的东西呢?”

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- But it's not that straightforward. - To see why, let's do some examples. So say alpha x is 1 and beta equals minus 1. Well, then, we get 1 squared, which is 1, equals minus 1 squared, which is also 1, so that satisfies the top equation. But if we fill it in here, we get 1 times minus 1, which is just minus 1, plus minus 1 times 1, which is, again, minus 1, for a total of minus 2. So, that doesn't work. So, let's try another number. Say alpha x is 1, and now it's alpha z that is minus 1. Well, in that case, we get 1 times minus 1. So, again, we get minus 1, plus minus, 1 times 1, again, minus 1. So we, again, get minus 2. And in fact, if you look at this top equation, the only numbers that satisfy this relation is 1 and minus 1. So all these coefficients have to be either 1 or minus 1, but if you fill that in, then the only two possible answers you're gonna get in these equations is minus 2 or positive 2. Now, the two equations that are giving problems are these two, and that's because alpha times beta is the same as beta times alpha. So, you're always gonna get minus 2 or 2. So, the only way to get out of this is to somehow make the order of multiplication matter. But where do you find something like that? (pensive music)

让我们思考一个非常简单的向量,比如x方向上的1和y方向上的2。如果我沿着y等于x的线反射这个向量,然后沿着x轴反射它,我得到这个。但如果我重新开始,而是先沿着x轴反射它,然后沿着y等于x的线反射它,我得到这个,这完全不同。所以,顺序很重要。我们如何用数学来表达这一点?我们需要某种方法来将变换,比如反射,表示为单个系数,这意味着我们需要矩阵(Matrices: 数学中由数字、符号或表达式排列成的矩形阵列,用于表示线性变换)。矩阵是数字的数组,它们封装了这些变换,告诉我们如何在每个维度上反射、旋转、拉伸或挤压。在数学上,我们乘法的顺序很重要。因为我们用第一个矩阵的行乘以第二个矩阵的列。

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- Let's think about a really simple vector, say 1 in the x-direction and 2 in the y-direction. If I reflect this vector along the line y equals x and then reflect it about the x-axis, I get this. But if I start again and instead reflect it first about the x-axis and then along y equals x, I get this, which is totally different. So, the order matters. How do we express this mathematically? We need some way to represent transformations, like reflections as a single coefficient, which means we need matrices. Matrices are arrays of numbers which encapsulate these transformations, telling us how to reflect, rotate, stretch, or squish across each dimension. Mathematically, the order we multiply them matters. Since we multiply the rows of the first matrix by the columns of the second, (pensive music)

一个沿着y等于x反射的矩阵看起来像这样,一个沿着x轴反射的矩阵看起来像这样。如果我将它们逐个应用于原始向量,你可以看到我们是如何得到不同结果的。

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(graphic whooshing) A matrix that reflects along y equals x looks like this and a matrix that reflects about the x-axis looks like this. (pensive music) And if I apply them to that original vector one by one, you can see how we end up with different results. (pensive music)

实际上,在量子力学中使用矩阵并不是完全出乎意料。狄拉克已经看到他的新朋友,尽管不太可能的朋友,维尔纳·海森堡这样做过。狄拉克和海森堡是截然不同的人物。海森堡迷人而外向,狄拉克讨厌社交和闲聊。有一次,两人一起乘坐游轮去参加一个会议,海森堡花了很多时间与船上的女士跳舞。于是狄拉克问他:“你为什么跳舞?”海森堡回答说:“有漂亮的女孩时,这是一种乐趣。”狄拉克思考了一会儿,然后说:“你怎么事先知道女孩很漂亮?”所以,他们是截然不同的人,但海森堡对狄拉克产生了深远的影响。

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And actually, using matrices in quantum mechanics was not completely out there. Dirac had already seen it done by Werner Heisenberg, his new, if unlikely, friend. Dirac and Heisenberg were very different characters. Heisenberg was charming and outgoing, Dirac hated socializing and small talk. Once the two were on a cruise ship to a conference together and Heisenberg spent a lot of time dancing with women on board. So, Dirac asked him, "Why do you dance?" Heisenberg replied, "When there are nice girls, it is a pleasure." Dirac thought about this for a bit before saying, "How do you know beforehand that the girls are nice?" So, they were pretty different guys, but Heisenberg had a profound impact on Dirac. (upbeat music)

“你知道最初是什么吸引他进入量子力学吗?”“他总是说海森堡给了他一个开始,他总是这么说。晚年,他70岁甚至80岁的时候,他会用以下的话开始讲座:‘量子力学是海森堡在1925年发现的。’”作为一名博士生,狄拉克密切关注了海森堡的工作,几年前,海森堡发现对于某些性质,比如位置和动量,乘法的顺序很重要。所以x乘以p不等于p乘以x。这实际上是海森堡著名的不确定性原理(Uncertainty Principle: 量子力学中,某些物理量对不能同时被精确测量,如位置和动量)的开端,它指出在量子系统中,我们能精确了解某些物理量对的程度是有限的。事实证明,如果两个性质(如位置和动量)的乘法顺序很重要,那么这意味着它们的组合测量存在固有的不确定性。我们测量它们的顺序会改变结果。海森堡的导师马克斯·玻恩(Max Born: 德国物理学家,量子力学的创始人之一,诺贝尔物理学奖得主)建议他可以通过使用矩阵来数学地表示这一点,因为在矩阵中,乘法的顺序也很重要。

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- Do you know what drew him to quantum mechanics initially? - He always said that Heisenberg gave him his start, he always said that. In later life, he used to begin lectures when he was 70, even 80 years old, with the following words. - Quantum mechanics was discovered by Heisenberg in 1925. - As a PhD student, Dirac had closely followed Heisenberg's work, and a few years earlier, Heisenberg had founded for certain properties, like position and momentum. The order of multiplication matters. So x times p is not the same as p times x. This was actually the beginning of Heisenberg's famous uncertainty principle, which says that there's a limit to how precisely we can know certain pairs of physical properties in quantum systems. It turns out that if the order of multiplication matters for two properties like position and momentum, then that means there's an inherent uncertainty in their combined measurements. The order we measure them in will change the outcome. Heisenberg's mentor, Max Born, suggested that he could represent this mathematically by using matrices, because there, the order of multiplication also matters. (pensive music)

这导致海森堡提出了一种新的量子力学形式,它在数学上等同于薛定谔方程,但它是基于矩阵代数。

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This led Heisenberg to a new form of quantum mechanics, which was mathematically equivalent to Schrodinger's equation, but it was based on matrix algebra.

狄拉克在他的系数中发现了类似之处,其中乘法的顺序显然很重要。所以他认为矩阵可能是解决方案。对于他的系数,他尝试了2x2矩阵,因为它们是最小、最简单的矩阵,可以使乘法的顺序变得重要。他发现有些矩阵适用于方程。事实上,我们之前尝试的那些反射矩阵效果很好,但他就是找不到所有四个系数都能协同工作的解决方案。

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- Dirac recognized something similar in his coefficients where the order of multiplication clearly mattered. So, he thought matrices might be the solution. For his coefficients, he tried 2x2 matrices since they're the smallest, simplest matrices that could make the order of multiplication matter. He found that some worked with the equations. In fact, those reflection matrices we tried earlier worked well, but he just couldn't find solutions for all four coefficients that all worked together.

“这并不简单。狄拉克是20世纪物理学中最聪明的人之一,对吧?但这并不容易。你不能只是修修补补薛定谔方程的某些部分。你必须做一些完全激进的事情。他的工作就在那里,你可以看到他真的在挣扎。”

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- So this is not simple. Dirac is one of the smartest people of the 20th century in physics, right? But it was not easy. You don't have just to twiddle with bits of the Schrodinger equation. You'd have to do something completely radical. His working is in there, and you could see him really struggling.

然后,狄拉克灵光一现。他说:“我突然意识到,没有必要只局限于可以用只有两行两列的矩阵表示的量。为什么不使用四行四列的矩阵呢?”

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- Then, Dirac had a stroke of genius. He said, "I suddenly realized that there was no need to stick to quantities, which can be represented by matrices with just two rows and columns. Why not go to four rows and columns?" (compelling music)

有了这四个4x4矩阵,狄拉克得到了他的联立方程的这些解,一个对角线上都是1的矩阵在数学上等同于1,而一个全是0的数组与0是相同的。所以,所有的方程都得到了满足。狄拉克找到了可行的系数。现在,我们可以将这些矩阵代回狄拉克的线性方程,然后将三个动量和alpha系数改写成向量。就像我们对薛定谔方程和克莱因-戈登方程所做的那样,我们可以使用能量和动量算符使方程两边作用于波函数。如果我们代入这些算符,我们就能得到狄拉克关于相对论自由电子的最终方程。

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With these four 4x4 matrices, Dirac got these solutions to his simultaneous equations, a matrix with 1s on the diagonal is mathematically equivalent to a 1, and a whole array of 0s is the same thing as 0. So, all of the equations were satisfied. Dirac had found coefficients that worked. Now, we can substitute those matrices back into Dirac's linear equation, then rewrite the three momenta and alpha coefficients as vectors. And just as we did with the Schrodinger and Klein-Gordon equations, we can use the energy and momentum operators to make both sides act on the wave function. If we substitute those operators in, we get Dirac's final equation for the relativistic free electron. (compelling music)

这位一生都在寻找数学之美的年轻人,也许找到了他所有方程中最美丽的一个。

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The young man who spent his life looking for mathematical beauty had found, perhaps, his most beautiful equation of all.

“人们期望这个解会很糟糕,结果却是一个美丽的东西,对吧?你看着它,你会想,‘那真是太棒了。’这是狄拉克在自然深处发现的一种模式。当时物理学中从未见过这样的东西。”

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- The people were expecting the solution to be horrible, and it turned out to be a thing of beauty, right? It was something you look at and you think, "That is absolutely amazing." It's a pattern that Dirac found deep in nature. Nothing like that has been seen in physics at that time. (suspenseful music)

要看到其中一些美,你只需将其与薛定谔方程进行比较,你可以在这里看到。现在,两者看起来非常相似,但狄拉克方程(Dirac Equation: 描述相对论性电子运动的量子力学方程,预测了反物质的存在)中隐藏着很多东西。首先,它是相对论性的,所以它在非常非常高的速度下也能工作,因为它使用了爱因斯坦的能量动量关系,而薛定谔方程在那里就会失效。但更美妙的是,如果你看这个,狄拉克方程不仅在时间导数上是一阶的,它在空间导数上也是一阶的。而薛定谔方程在空间导数上是二阶的。所以你可能会想,“嗯,那有什么关系呢?”

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- To see some of that beauty, you only have to compare it to the Schrodinger equation, which you can see right here. Now, the two look very similar, but there is a lot hidden in the Dirac equation. First of all, it's relativistic, so it works at really, really high speeds because it uses Einstein's energy momentum relationship, unlike the Schrodinger equation which breaks down there. But what's even more beautiful is that if you look at this, Dirac's equation isn't just first order in time derivatives, it's also first order in spatial derivatives. Whereas the Schrodinger equation was second order in spatial derivatives. So you might wonder, "Well, why does that matter?"

嗯,因为所有导数都变成一阶不仅解决了克莱因-戈登方程的二阶时间导数问题,它现在还对称地处理时间和空间。如果你开始思考相对论,这变得非常重要,因为时间和空间不是独立的维度,它们在四维时空中相互交织。虽然薛定谔方程只有一个分量波函数,但在狄拉克的情况下,为了使波函数与这些4x4矩阵一起工作,你实际上需要一个具有四个分量的波函数。所以,它看起来会像这样:psi一、psi二、psi三和psi四。

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Well, because not only does going first order in all derivatives solve the second-order time derivative problem of the Klein-Gordon equation, it now also treats time and space symmetrically. And it becomes really important if you start thinking about relativity, where time and space are not separate dimensions, they're intertwined in a four dimensional spacetime. And while the Schrodinger equation had just a single component wave function, to make the wave function work with these 4x4 matrices, in Dirac's case, you actually need a wave function that has four components. So, it'll look something like this. Psi one, psi two, psi three, and psi four.

四分量波函数意味着狄拉克方程描述了任何量子系统的四种可能状态,这揭示了薛定谔的单波函数没有揭示的东西。一个给定能级的电子实际上有两种可能的状态,这是由于其内在角动量(自旋(Spin: 粒子的一种内在量子属性,类似于角动量)向上和自旋向下)的不同方向造成的。

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- The four-component wave function means that the Dirac equation describes four possible states for any quantum system, which reveals something Schrödinger's single wave function didn't. An electron at a given energy level actually has two possible states due to different orientations of its intrinsic angular momentum, spin up and spin down. (pensive music)

这种自旋产生了一个微小的磁场。所以这两种状态就像指向相反方向的微小磁铁,这有一个有趣的含义。以氢为例,它有一个质子和一个电子。经典地,电子绕着质子旋转。但如果你切换到电子的视角,那么现在是质子在移动。由于它带正电荷,这种移动的电荷在电子的参考系中产生了一个磁场。所以,现在你有一个电子,它有自己的微型磁场,与一个更大的磁场相互作用,这种相互作用对于自旋向上和自旋向下的电子会略有不同。结果,电子的一些能级分裂成两个紧密间隔的能级。如果你放大氢原子的发射光谱,你实际上可以看到这一点。

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This spin creates a tiny magnetic field. So these two states are like tiny magnets pointing in opposite directions, and that has an interesting implication. Take hydrogen, which has one proton and one electron. Classically, the electron whizzes around the proton. But if you switch to the perspective of the electron, well, now, it's the proton that's moving. And since it's positively charged, that moving charge creates a magnetic field in the electron's frame of reference. So, now you've got this electron, which has its own mini magnetic field, interacting with a larger magnetic field, and that interaction will be slightly different for a spin up and a spin down electron. And as a result, some energy levels of the electron split into two closely-spaced energy levels. And you can actually see this if you zoom into the emission spectrum for a hydrogen atom. (suspenseful music)

薛定谔方程没有预测这种分裂,因为它对每个能级只有一个解。但有了狄拉克的四分量解,上面两个波函数现在描述了两种不同的自旋状态,具有两种略微不同的能量。

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Schrödinger's equation didn't predict that splitting since it just had one solution for each energy level. But with Dirac's four-component solution, the top two wave functions now described two different spin states with two slightly different energies.

狄拉克自己承认,他从未打算在他的方程中捕捉到自旋。“我开始这项工作时,根本没有打算引入电子的自旋。”卡斯珀说:“但是等等,因为如果一个给定能级的电子只有两种可能的自旋状态,那么我们为什么会有四分量波函数呢?为什么有四种状态而不仅仅是两种呢?”

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- Dirac admitted himself that he had never set out to capture spin in his equation. - I started out this work without any intention at all of bringing in the spin of the electron. - [Casper] But hold on, because if an electron at a given energy level only has two possible spin states, then why do we have a four-component wave function? Why are there four states and not just two? (compelling music)

负能量解与反电子的预测

德里克说:“嗯,这让我们回到了开头1928年的那场讲座,那场似乎让最资深的量子物理学家都发疯的讲座。因为那个展示他工作的奇怪男人,实际上就是保罗·狄拉克,他正在向世界分享他的新方程。正是狄拉克美丽的方程被海森堡称为‘现代物理学中最悲伤的一章’。”

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- [Derek] Well, that's what brings us back to that 1928 lecture at the start, the one that seemed to drive even the most well-established quantum physicists mad. Because that strange man presenting his work was actually Paul Dirac sharing his new equation with the world. It was Dirac's beautiful equation that Heisenberg called, "The saddest chapter in modern physics." (somber music)

要理解为什么所有这些物理学家都快疯了,我们只需看看粒子静止时的简单情况。这里这个项描述了动量。所以,当粒子不动时,这个项变为0并消失,这就得到了这个。接下来,我们可以将能量代入这个量子算符,得到这个。所以现在我们知道beta乘以mc²必须等于粒子的能量。如果我们写出beta并乘以mc²,那么我们发现能量有两个正解和两个负解。所以,负能量解直接嵌入在狄拉克方程中。

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- To understand why all those physicists were losing their minds, we only have to look at the simple case when a particle is at rest. This term right here describes the momentum. So, when the particle doesn't move, this becomes 0 and it drops out, which gives us this. Next, we can sub in the energy for this quantum operator to get this. So now, we know that beta times mc squared must be equal to the particle's energy. And if we write out beta and multiplied by mc squared, then we find two positive solutions and two negative solutions for the energy. So, negative energy solutions are baked right into the Dirac equation. (pensive music)

一个自由电子可以有负能量这个想法,是这些物理学家无法接受的。因为想想看。如果电子可以有负能量,那么这意味着它们可以持续辐射正能量,也就是发射光子,并落入越来越低的负能量状态。它们可以无限地坠入负能量深渊。

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This idea that a free electron could have negative energy was impossible for any of these physicists to accept. Because think about it. If electrons can have a negative energy, then that means that they could continually radiate positive energy, that is emit photons, and drop into lower and lower negative energy states. There would be no limit to how far they could fall into the negative energy abyss. (compelling music)

“对许多非常聪明的人来说,看起来是这样,而狄拉克也足够聪明,知道他们有道理,这个方程,它得到了电子的质量和磁矩。是的,但另一方面,它预测了这种荒谬的情况,即你有负能量值。”“对。”“那真是胡说八道。所以海森堡说:‘我放弃了。这太荒谬了。’所以,狄拉克,从某种非常明确的意义上说,他必须拯救他的方程。”

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- It looked like, to many very smart people, and Dirac was smart enough to know they had a point, that this equation, it got the mass and the magnetic moment of the electron. Yes, but on the other hand, it predicts this ridiculous situation, where you have negative energy values. - Right. - That's nonsense. So, Heisenberg said, "I give up. This is just ridiculous." So, Dirac, he had, in some very clear sense, had to rescue his equation. (pensive music)

德里克说:“狄拉克花了三年时间坚持自己的观点。他尝试了各种方法来解释他的新方程,以解释负能量的来源。然后,在1931年,他提出了一个激进的想法来解释负能量解:一种实验物理学未知的新粒子,具有与电子相同的质量和相反的电荷。我们可以称这种粒子为反电子(Anti-electron: 电子的反粒子,即正电子)。我们不应该期望在自然界中找到它们,因为它们与电子的复合速度很快。”

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- [Derek] Dirac spent three years sticking to his guns. He tried all sorts of ways to interpret his new equation to explain where the negative energy was coming from. Then, in 1931, he proposed something radical to explain the negative energy solutions. (suspenseful music) A new kind of particle unknown to experimental physics, having the same mass and opposite charge to an electron. We may call such a particle an anti-electron. We should not expect to find any of them in nature on account of their rapid rate of recombination with electrons. (suspenseful music)

所以,狄拉克提出,他的四分量波函数中描述的四种状态是:一个自旋向上的电子,一个自旋向下的电子,一个自旋向上的反电子,以及一个自旋向下的反电子。

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So, Dirac was proposing that those four states described in his four-component wave function are a spin up electron, a spin down electron, a spin up antielectron, and a spin down antielectron.

“当狄拉克说出这话时,人们并没有开始跑来跑去说:‘这个反电子在哪里?’他们只是忽略了它。”“是的。”“转到加州理工学院的实验室。”

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- When Dirac said that, people didn't start running around saying, "Where's this antielectron?" They just ignored it. - Yeah. - Cut to the laboratory at Caltech.

正电子的意外发现

1932年,加州理工学院(Caltech: California Institute of Technology,美国著名的私立研究型大学)博士后卡尔·安德森(Carl Anderson: 美国物理学家,正电子的发现者,诺贝尔物理学奖得主)正在进行一个项目,试图识别宇宙射线产生的带电粒子。他拍摄了这些粒子在含有均匀磁场的云室中留下的轨迹。安德森注意到有几个相似的轨迹。它看起来很像他以前见过的电子留下的轨迹。只是,它在磁场中向相反方向弯曲。有点像带正电荷的质子(Proton: 带正电荷的亚原子粒子)的轨迹。但根据轨迹的长度,它不可能是质子。它在空气中传播得更远,因此它必须轻得多。它必须是质量与电子相似但电荷相反的东西。一个带正电荷的电子,或者他命名为正电子(Positron: 电子的反粒子,带正电荷)。他实际上也试图将电子重新命名为负电子,但那个名字没有流行起来。就在狄拉克提出反电子一年后,卡尔·安德森完全是偶然地发现了它。

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- In 1932, a Caltech postdoc named Carl Anderson was working on a project trying to identify the charge particles produced by cosmic rays. He photographed the tracks these particles left in a cloud chamber containing a uniform magnetic field. Anderson noticed several instances of a similar track. It looked a lot like the tracks he'd seen left by electrons. Only, it curved in the opposite direction in the magnetic field. Kind of like the tracks of positively charged protons. But there was no way it could be a proton based on the length of the track. It had traveled farther in air, and therefore it had to be much lighter. It had to be something with around the same mass as an electron, but opposite charge. A positive electron, or as he named it, a positron. He actually also tried to rebrand electrons as negatrons, but that one didn't quite stick. Just one year after Dirac proposed the antielectron, Carl Anderson found it entirely by accident. (uplifting music)

但这本身并不能消除负能量问题。还记得我们之前说过什么吗?如果任何粒子,比如这些正电子,可以有负能量,那么它们就可以持续辐射能量并落入越来越低的负能量状态。幸运的是,狄拉克也提出了这个问题的解决方案,尽管它有点疯狂。

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- But this alone doesn't get rid of the negative energy problem. Remember what we said earlier. If any particles, like these positrons, can have negative energy, then they could continually radiate energy and drop into lower and lower negative energy states. Fortunately, Dirac proposed a solution to this problem as well, although it was a little crazy. (suspenseful music)

负能量的解释:狄拉克海与费曼图

他理论化了一种被称为狄拉克海(Dirac Sea: 狄拉克提出的一个理论模型,假设真空充满了负能量电子,以解释负能量解和反粒子)的东西,将真空描述为无限的电子海洋,占据所有可用的负能量状态。由于没有两个电子可以占据相同的状态,这阻止了可观测的正能量电子落入负能量状态。这个海洋中的一个空穴或空位就变成了一个正电子。当一个电子和一个正电子相遇并湮灭(Annihilate: 粒子与反粒子相遇时相互抵消并转化为能量的过程)时,那只是一个电子落回海洋并填补那个空穴。这个理论在数学上是严谨的。当然,我们谈论的是狄拉克,但如果你觉得很难接受我们漂浮在一个无限的电子海洋上的想法,那么你并不孤单。

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- He theorized something called the Dirac sea, describing a vacuum as an infinite sea of electrons occupying all available negative energy states. And since no two electrons can occupy the same state, this prevents observable positive energy electrons from falling into the negative energy states. A hole or vacancy in this sea then becomes a positron. When an electron and a positron meet and annihilate, well, that's just an electron falling back into the sea and filling that hole. The theory is mathematically sound. Of course, it's Dirac we're talking about, but if you feel like it's hard to come to terms with the idea that we're floating on an infinite sea of electrons, well, you wouldn't be alone.

“如果几十年后,人们在物理系统中发现完全相同的模型,那甚至不算太疯狂。在凝聚态物理学中,你会看到一个完全类似的类比,也有导带中的电子和价带中的电子。”“是的,那是真的。那是真的。但狄拉克真的,你知道,很超前。你明白我的意思吗?也许是像……他没有看到,真的看到人们在说:‘这真是胡说八道。’但这是狄拉克直线思维的一种方式,他想:‘嗯,也许这是……’然后它把他引向了反物质(Antimatter: 由反粒子组成的物质,与普通物质具有相同质量但电荷相反)。”

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- It's not even that crazy if, I don't know, several decades later, people find that exact model in a physical system. In condensed matter physics, you see an exact analogy of also having electrons in the conduction band and say valence-covalence band. - Yes, that's true. That's true. But Dirac really was, you know, out there. You see what I mean? Maybe it was people like... He doesn't see it, really seeing that people are saying, "This is nonsense." But it was a way of Dirac's rectilinear thinking, thinking, "Well maybe this is..." And then it drove him to antimatter.

值得庆幸的是,1941年,瑞士物理学家恩斯特·斯图克尔伯格(Ernst Stueckelberg: 瑞士物理学家,提出了反粒子可以解释为负能量粒子逆时间旅行的观点)有一个巧妙的想法。波函数包含一个像这样的项,其中能量乘以时间。所以,我们可以看到,如果我们只是在能量为负时改变时间的符号,那么我们就会得到相同的结果,因为负数乘以负数会得到正数。斯图克尔伯格采纳了这个想法,他提出负能量电子逆时间旅行在数学上等同于正能量反电子(Antielectrons: 电子的反粒子,即正电子)顺时间旅行。

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- Thankfully, in 1941, a Swiss physicist named Ernst Stueckelberg had a clever idea. The way function contains a term that looks like this, where energy is multiplied by time. So, we can see that if we just change the sign of time when the energy is negative, then we get the same result because a negative multiplied by a negative gives us a positive. Stueckelberg took this, and he suggested that negative energy electrons traveling backwards in time are mathematically equivalent to positive energy antielectrons, that is positrons, traveling forwards in time.

几年后,大约在1948年,理查德·费曼(Richard Feynman: 美国理论物理学家,量子电动力学的创始人之一,诺贝尔物理学奖得主)采纳了这个想法,并将其用于现代物理学中最强大的工具之一,即费曼图(Feynman Diagrams: 费曼发明的一种图形表示方法,用于描述亚原子粒子之间的相互作用)。在他的粒子相互作用草图中,他展示了反粒子(Antiparticle: 与普通粒子质量相同但电荷相反的粒子)逆时间旅行,与粒子方向相反。

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- A few years later, around 1948, Richard Feynman took this idea and used it in one of the most powerful tools in modern physics, the Feynman diagrams. In his sketches of particle interactions, he showed antiparticles traveling the opposite way to particles backwards in time. (pensive music)

这是一个绝妙的技巧。负能量解不再意味着存在负能量或狄拉克海。它们只是简单地表明存在一个反粒子。

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It was a brilliant trick. Negative energy solutions no longer had to mean there was negative energy or a Dirac sea. They simply indicated the presence of an antiparticle. (suspenseful music)

我们现在知道,每个亚原子粒子都有一个对应的反粒子,它们具有相同的质量,但电荷相反。所以,质子(Proton: 带正电荷的亚原子粒子)有反质子(Antiproton: 质子的反粒子,带负电荷),中微子(Neutrino: 一种不带电荷、质量极小的亚原子粒子)有反中微子(Antineutrino: 中微子的反粒子),等等。

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We now know that there's a corresponding antiparticle for every subatomic particle, with the same mass, but opposite charge. So, the proton has the antiproton, the neutrino has the antineutrino, and so on.

根据他的朋友海森堡的说法,这是20世纪物理学中最大的飞跃,即存在一整套与粒子对应的反粒子,而狄拉克通过这个疯狂的模型得到了这一点。

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- According to his friend, Heisenberg, that was the biggest leap in 20th-century physics to say there's a whole slew of antiparticles corresponding to particles, and Dirac got that through this crazy model. (pensive music)

宇宙的未解之谜:物质-反物质不对称

但并非所有问题都已解决。这个新的反世界引入了一些关于我们宇宙本质的重大问题。因为粒子和它们的反粒子是相等且相反的,当它们结合时,它们会湮灭(Annihilate: 粒子与反粒子相遇时相互抵消并转化为能量的过程)并产生两个光子,其能量相当于它们的质量和动能。这个过程是可逆的。两个具有正确能量的光子可以产生一对物质和反物质。这被称为布赖特-惠勒对产生(Breit-Wheeler Pair Production: 两个光子相互作用产生一对物质-反物质粒子的过程)。

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- But all is not solved. This new antiworld introduces some big questions about the very nature of our universe. Because particles and their antiparticles are equal and opposite, when they come together, they annihilate and produce two photons with energy equivalent to their mass and kinetic energy. And this process is reversible. Two photons with the right energies can produce a matter and antimatter pair. This is called Breit-Wheeler pair production. (suspenseful music)

大爆炸(Big Bang: 宇宙起源的理论,认为宇宙从一个极热、极密的初始状态膨胀而来)后的最初时刻,宇宙是炽热、致密的,充满了这些不断产生和消失的粒子对。如果产生了等量的物质和反物质粒子,你就会期望它们在这个致密的环境中全部相互湮灭,只留下能量。但那没有发生。我们最终得到了一个充满物质的宇宙。如果我们从今天宇宙中物质和反物质的量倒推,实际上估计每十亿个物质粒子中只有一个粒子需要在这个炽热、致密的时代中幸存下来,没有被湮灭。这种微小的差异将构成我们今天的宇宙,其中物质占据主导地位。

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(Big Bang exploding) During the first moments after the Big Bang, the universe was hot, dense, and full of these pairs popping into and out of existence. If an equal number of matter and antimatter particles were created, you would expect them to all annihilate each other in this dense environment, leaving behind only energy. But that didn't happen. We ended up with a universe full of matter. If we work backwards from how much matter and antimatter is in the universe today, it's actually estimated that only one particle per billion of matter needed to survive this hot, dense era and not get annihilated. That tiny difference would give us the makeup of our universe today, where matter dominates.

那么,是什么让每十亿个粒子中那一个粒子逃脱了湮灭呢?为什么物质战胜了反物质?

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- So what allowed that one particle per billion to escape annihilation? Why did matter win out over antimatter? (compelling music)

嗯,这是一个相当大的问题,答案并不那么简单。所以,我们正在制作一个完整的第二部视频,其中有一些相当壮观的事情发生。我们正在深入研究这个庞然大物。这绝对是疯狂的。我感觉我不应该在这里。所以你在制造反原子吗?“是的。”卡斯珀说:“太酷了。”

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Well, that's a pretty big question with some not so simple answers. So, we're doing an entire second video where we have some pretty spectacular stuff happening. We're getting into the beast. It's absolutely insane. I feel like I should not be in here. So you're making anti-atoms? - Yes. (energy humming) - [Casper] It's so cool. (compelling music)

狄拉克的遗产与个人生活

狄拉克可能不如海森堡或薛定谔等人出名,但他对量子物理学的贡献是巨大的,他也因此获得了认可。他与薛定谔共同获得了1933年的诺贝尔奖(Nobel Prize: 瑞典化学家阿尔弗雷德·诺贝尔设立的国际奖项,表彰在物理、化学、生理学或医学、文学、和平及经济学领域做出杰出贡献的人),以表彰他们发现了原子理论的新生产形式。也许这给了奇怪而安静的狄拉克一些新的信心,因为开头1928年讲座的听众中的那位物理学家尤金·维格纳,后来实际上成为了狄拉克的好朋友。1934年,维格纳将狄拉克介绍给了他的妹妹玛吉特·维格纳(Margit Wigner: 尤金·维格纳的妹妹,保罗·狄拉克的妻子),一个可能比任何方程或诺贝尔奖更能改变狄拉克生活的女人。

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- Dirac is probably less well-known than people like Heisenberg or Schrödinger, but his contribution to quantum physics was immense, and he was recognized for it. He shared the 1933 Nobel Prize with Schrödinger for the discovery of new productive forms of atomic theory. And perhaps this gave strange, quiet Dirac some newfound confidence, because that physicist in the audience of his 1928 lecture at the start, Eugene Wigner, actually became a reasonable friend of Dirac's. And in 1934, introduced Dirac to his sister, Margit Wigner, a woman who would change Dirac's life, perhaps more than any equation or Nobel Prize. (pensive music)

“他们是反粒子,对吧?他们有着完全不同的个性。他几乎没有同理心,对吧?他知道这一点。她却充满了同理心。他几乎不说话,她却说个不停。你可以一直说下去,他们是完全不同的人。但婚姻确实成功了。我的好朋友莉莉亚·哈里斯·钱德拉,她认识他们,她说过一句很棒的话,很棒的话,那就是:‘他给了她地位,她给了他生活。’”

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- They were antiparticles, right? They had completely different personalities. He had almost no empathy, right? And he knew it. She had buckets of it. He hardly talked, she couldn't stop talking. You could just go on, like they are completely different people. But the marriage did work. My great friend Lilia Harris Chandra, who knew them, she came out with a great line, great line, which is, "He gave her status, she gave him a life."

所以,我想有一对粒子-反粒子从未湮灭。

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- So, I guess there is one particle-antiparticle pair that never annihilated. (pensive music) (graphic beeping) (pensive music)

嘿,最后一件事,如果你还不知道的话,我们刚刚推出了官方的Veritasium游戏。它有800个问题,是挑战朋友的完美方式。每次我们在Veritasium玩它,气氛都会有点紧张,那真是太有趣了。如果你想去看看,那就前往我们的Kickstarter,在那里你可以预订自己的版本。现在,我们已经开通了全球发货,所以无论你身在世界何处,你都可以获得自己的版本。我们即将迎来Kickstarter活动的最后几天。所以,这是你获得独家首发版的最后机会。所以,如果你想支持我们,请点击描述中的链接或扫描此二维码前往Kickstarter。我要感谢大家的所有支持,最重要的是,感谢您的观看。

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- Hey, one last thing, in case you didn't already know, we just launched the official Veritasium game. It comes with 800 questions, and it's the perfect way to challenge your friends. Every time we play it at Veritasium, things get a little bit heated, and that is so much fun. If you want to go check it out, then head over to our Kickstarter, where you can pre-order your own version. And right now, we've enabled global shipping, so no matter where you are in the world, you can get your own version. We're coming close to the final few days of the Kickstarter campaign. So, this is your last chance to get your hands on the exclusive launch edition. So, if you wanna support us, head over to Kickstarter by clicking the link in the description or scanning this QR code. I wanna thank you for all your support, and most of all, thank you for watching.

关键字: antimatter-discovery energy matter-antimatter-asymmetry science technology